Umpolung reactivity of strained C–C σ-bonds without transition-metal catalysis

Abstract Umpolung is an old and important concept in organic chemistry, which significantly expands the chemical space and provides unique structures. While, previous research focused on carbonyls or imine derivatives, the umpolung reactivity of polarized C–C σ-bonds still needs to explore. Herein,...

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Detalles Bibliográficos
Autores principales: Dachang Bai, Xiuli Guo, Xinghua Wang, Wenjie Xu, Ruoshi Cheng, Donghui Wei, Yu Lan, Junbiao Chang
Formato: Artículo
Lenguaje:English
Publicado: Nature Portfolio 2024-04-01
Colección:Nature Communications
Acceso en línea:https://doi.org/10.1038/s41467-024-47169-9