Free Radical Isomerizations in Acetylene Bromoboration Reaction

The experimentally motivated question of the acetylene bromoboration mechanism was addressed in order to suggest possible radical isomerization pathways for the <i>syn</i>-adduct. Addition–elimination mechanisms starting with a bromine radical attack at the “bromine end” or the “boron en...

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Bibliographic Details
Main Authors: Hugo Semrád, Ctibor Mazal, Markéta Munzarová
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/9/2501