17O NMR of Enamino-Diesters: Intramolecular Hydrogen Bonding in 5-Alkylaminomethylene-2,2-dimethyl-1,3-dioxane-4,6-diones

Natural abundance 17O NMR spectra of a series of 5-alkylaminomethylene-2,2-dimethyl-1,3-dioxane-4,6-diones, recorded in acetonitrile solution, are reported. The δ(17O) values correlate well with those of 4-alkylaminobut-3-en-2-ones and with the pKa values of amines. The effects of the N-alkyl gro...

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Bibliographic Details
Main Author: Jin-Cong Zhuo
Format: Article
Language:English
Published: MDPI AG 1997-02-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/2/2/31/