Synthesis and crystal structures of extremely bulky phosphinoamido and phosphinoamino germanium(II) chloride complexes

Reaction of an extremely bulky potassium amide complex, KL† (L†=[Ar†(PPh2)N]-, Ar†=C6H2{C(H)Ph2}2Pri-2,6,4), with GeCl2·dioxane afforded low yields of the phosphinoamido and phosphinoamino germanium(II) chloride complexes, [GeCl2(κ1-P-L†GeCl)] and [GeCl2(κ1-P-L†H)], respectively. The X-ray crystal s...

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Bibliographic Details
Main Authors: Böttcher Tobias, Jones Cameron
Format: Article
Language:English
Published: De Gruyter 2015-12-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2015-0026