Synthesis, Characterization and Reactions of (Azidoethynyl)trimethylsilane

Synthesis of azido(trimethylsilyl)acetylene (6) was performed by treating the iodonium salt 5 with highly soluble hexadecyltributylphosphonium azide (QN3) at −40 °C. Although this product is very unstable, it can nevertheless be trapped by the click reaction with cyclooctyne to give the correspondin...

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Bibliographic Details
Main Authors: Klaus Banert, Manfred Hagedorn, Zhuang Wu, Xiaoqing Zeng
Format: Article
Language:English
Published: MDPI AG 2015-12-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/20/12/19770