Stereoisomeric Tris-BINOL-Menthol Bulky Monophosphites: Synthesis, Characterisation and Application in Rhodium-Catalysed Hydroformylation

Stereoisomeric Tris-BINOL-Menthol Bulky Monophosphites: Synthesis, Characterisation and Application in Rhodium-Catalysed Hydroformylation

Four stereoisomeric monoether derivatives, based on axially chiral (<i>R</i>)- or (<i>S</i>)-BINOL bearing a chiral (+)- or (−)-neomenthyloxy group were synthesised and fully characterised by NMR spectroscopy and X-ray crystallography. The respective tris-monophosphites were...

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Bibliographic Details
Main Authors: Alexandre P. Felgueiras, Fábio M. S. Rodrigues, Rui M. B. Carrilho, Pedro F. Cruz, Vitor H. Rodrigues, Tamás Kégl, László Kollár, Mariette M. Pereira
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Molecules
Subjects:
BINOL
menthol
X-ray diffraction
monophosphite synthesis
Mitsunobu reaction
DFT computational methods
Online Access:https://www.mdpi.com/1420-3049/27/6/1989

Internet

https://www.mdpi.com/1420-3049/27/6/1989

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