Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS
A survey was designed to investigate the pesticide residues in agricultural produce and to estimate their potential intake risks to inhabitants. A total of 314 samples of nine types of fruits and vegetables were collected from the supermarkets and vegetable markets of Shandong Province (China) from...
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| Format: | Article |
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MDPI AG
2023-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/6/2480 |
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| author | Yue Wang Tingjie Huang Tao Zhang Xiaoping Ma Guangshuo Zhou Meiyao Chi Xinjie Geng Chunhao Yuan Nan Zou |
| author_facet | Yue Wang Tingjie Huang Tao Zhang Xiaoping Ma Guangshuo Zhou Meiyao Chi Xinjie Geng Chunhao Yuan Nan Zou |
| author_sort | Yue Wang |
| collection | DOAJ |
| description | A survey was designed to investigate the pesticide residues in agricultural produce and to estimate their potential intake risks to inhabitants. A total of 314 samples of nine types of fruits and vegetables were collected from the supermarkets and vegetable markets of Shandong Province (China) from October 2020 to February 2022. An accurate and reliable multi-residue method, based on GC-MS/MS detection, as well as the multiplug filtration cleanup method, based on SBA-15-C<sub>18</sub>, was prepared by a solution chemical reaction. Additionally, an in situ co-condensation method was established for the quantification of 139 pesticide residues. Residues that contained no pesticides were detected in 66.5% of the 314 samples. Moreover, of the samples, 30.6% were at or below the MRLs, and 2.9% were above the MRLs. Residues of procymidone were found to be the one that most often exceeded the MRLs (1.3% of the samples). Tebuconazole was found most frequently in 22.0% of the samples analyzed. Consumer exposure to the 139 pesticides did not exceed 100% ADI and ARfD. This led to a consideration that these pesticide residues in the nine commodities may not raise the health risk of the consumers in the long and short term. The highest value of chronic dietary intake was obtained from spirodiclofen, which resulted in a 24.1% of ADI. Furthermore, the highest exposure levels in the short term were obtained from the consumption of leeks with procymidone (58.3% ARfD). |
| first_indexed | 2024-03-11T06:08:44Z |
| format | Article |
| id | doaj.art-d71627867a024fc8845d5b722cf458e2 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T06:08:44Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-d71627867a024fc8845d5b722cf458e22023-11-17T12:50:57ZengMDPI AGMolecules1420-30492023-03-01286248010.3390/molecules28062480Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MSYue Wang0Tingjie Huang1Tao Zhang2Xiaoping Ma3Guangshuo Zhou4Meiyao Chi5Xinjie Geng6Chunhao Yuan7Nan Zou8School of Chemistry and Pharmaceutical Engineering, Shandong First Medical University, Shandong Academy of Medical Sciences, Tai’an 271016, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaSchool of Chemistry and Pharmaceutical Engineering, Shandong First Medical University, Shandong Academy of Medical Sciences, Tai’an 271016, ChinaKey Laboratory of Pesticide Toxicology & Application Technique, College of Plant Protection, Shandong Agricultural University, Tai’an 271018, ChinaA survey was designed to investigate the pesticide residues in agricultural produce and to estimate their potential intake risks to inhabitants. A total of 314 samples of nine types of fruits and vegetables were collected from the supermarkets and vegetable markets of Shandong Province (China) from October 2020 to February 2022. An accurate and reliable multi-residue method, based on GC-MS/MS detection, as well as the multiplug filtration cleanup method, based on SBA-15-C<sub>18</sub>, was prepared by a solution chemical reaction. Additionally, an in situ co-condensation method was established for the quantification of 139 pesticide residues. Residues that contained no pesticides were detected in 66.5% of the 314 samples. Moreover, of the samples, 30.6% were at or below the MRLs, and 2.9% were above the MRLs. Residues of procymidone were found to be the one that most often exceeded the MRLs (1.3% of the samples). Tebuconazole was found most frequently in 22.0% of the samples analyzed. Consumer exposure to the 139 pesticides did not exceed 100% ADI and ARfD. This led to a consideration that these pesticide residues in the nine commodities may not raise the health risk of the consumers in the long and short term. The highest value of chronic dietary intake was obtained from spirodiclofen, which resulted in a 24.1% of ADI. Furthermore, the highest exposure levels in the short term were obtained from the consumption of leeks with procymidone (58.3% ARfD).https://www.mdpi.com/1420-3049/28/6/2480multiplug filtration cleanupSBA-15-C<sub>18</sub>pesticide residuedietary risk assessment |
| spellingShingle | Yue Wang Tingjie Huang Tao Zhang Xiaoping Ma Guangshuo Zhou Meiyao Chi Xinjie Geng Chunhao Yuan Nan Zou Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS Molecules multiplug filtration cleanup SBA-15-C<sub>18</sub> pesticide residue dietary risk assessment |
| title | Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS |
| title_full | Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS |
| title_fullStr | Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS |
| title_full_unstemmed | Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS |
| title_short | Residue Levels and Dietary Intake Risk Assessments of 139 Pesticides in Agricultural Produce Using the m-PFC Method Based on SBA-15-C<sub>18</sub> with GC-MS/MS |
| title_sort | residue levels and dietary intake risk assessments of 139 pesticides in agricultural produce using the m pfc method based on sba 15 c sub 18 sub with gc ms ms |
| topic | multiplug filtration cleanup SBA-15-C<sub>18</sub> pesticide residue dietary risk assessment |
| url | https://www.mdpi.com/1420-3049/28/6/2480 |
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