Radical character quenches luminescence in the all-hydrocarbon radical benzoBDPA

Radical character quenches luminescence in the all-hydrocarbon radical benzoBDPA

We have synthesized and characterized a benzannulated analog, bBDPA, of the well-known stable radical bis(diphenylene)phenylallyl (BDPA). Benzannulation gives rise to fluorescence in the closed-shell precursor molecule bBDPAH, but luminescence is quenched in the radical species. We detail the synthe...

Full description

Bibliographic Details
Main Authors: Adrian R. Birge, Matthew J. Piper, Karl J. Painter, Graham T. Sazama
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Results in Chemistry
Subjects:
Organic Radical
Luminescence
Fluorescence
Benzannulation
BDPA
Stable radicals
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715622001126

Internet

http://www.sciencedirect.com/science/article/pii/S2211715622001126

Similar Items