Synthesis of Functionalized 4-Aryl-2,3 Bis (Trifluoromethanesulfonyloxy) Benzophenones, Based on Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4-Tris (Trifluoromethanesulfonyloxy) Benzophenone.
Suzuki–Miyaura reactions of the tris(triflate) of 2,3,4-benzophenonewith one 1 equivalent of arylboronic acids afforded 4-aryal-2,3- bis(trifluoromethanesulfonyloxy)benzophenones with very good site selectivity favor of position C4 which is satirically less hindered than position C2.
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Format: | Article |
Language: | English |
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University of Zakho
2013-06-01
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Series: | Science Journal of University of Zakho |
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Online Access: | https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/94 |