Photoredox-enabled remote radical group migration: Pathway to 1,7-dicarbonyl compounds from diazoalkanes

Photoredox-enabled remote radical group migration: Pathway to 1,7-dicarbonyl compounds from diazoalkanes

Herein, we developed a mild and efficient photoredox-enabled remote radical group migration with the utilization of diazoalkanes as radical precursors, giving access to various valuable 1,7-dicarbonlys in moderate to good yields. A diverse set of migrating groups, including benzothiazole, benzothiop...

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Bibliographic Details
Main Authors: Hai-Bing Ye, Ye-Peng Bao, Tian-Yang Liu, Tao Wei, Chen Yang, Qing-An Liu, Jun Xuan
Format: Article
Language:English
Published: Elsevier 2023-08-01
Series:Tetrahedron Chem
Subjects:
1,n-dicarbonyls
Radical migration
Diazoalkanes
Visible light
Photoredox catalysis
Online Access:http://www.sciencedirect.com/science/article/pii/S2666951X23000062

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http://www.sciencedirect.com/science/article/pii/S2666951X23000062

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