Recent Advances in Organic-inorganic Hybrid Photoresists

Photoresists are radiation-sensitive materials used for forming patterns to build up IC devices. To date, most photoresists have been based on organic polymers, which have been dominating the semiconductor industries over the past few decades. It is obvious that extreme ultraviolet (EUV) lithography...

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Main Authors: Zhihao Wang, Xindi Yao, Huiwen An, Yake Wang, Jinping Chen, Shuangqing Wang, Xudong Guo, Tianjun Yu, Yi Zeng, Guoqiang Yang, Yi Li
Format: Article
Language:English
Published: JommPublish 2021-03-01
Series:Journal of Microelectronic Manufacturing
Subjects:
Online Access:http://www.jommpublish.org/p/69/
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author Zhihao Wang
Xindi Yao
Huiwen An
Yake Wang
Jinping Chen
Shuangqing Wang
Xudong Guo
Tianjun Yu
Yi Zeng
Guoqiang Yang
Yi Li
author_facet Zhihao Wang
Xindi Yao
Huiwen An
Yake Wang
Jinping Chen
Shuangqing Wang
Xudong Guo
Tianjun Yu
Yi Zeng
Guoqiang Yang
Yi Li
author_sort Zhihao Wang
collection DOAJ
description Photoresists are radiation-sensitive materials used for forming patterns to build up IC devices. To date, most photoresists have been based on organic polymers, which have been dominating the semiconductor industries over the past few decades. It is obvious that extreme ultraviolet (EUV) lithography has become the next-generation lithography technology. The development of comprehensive performance EUV resist is one of the most critical issues. However, organic polymeric photoresists are difficult to meet the harsh requirements of EUV lithography. Pure inorganic photoresists such as metal salts, hydrogen silsesquioxane (HSQ) are expected for EUV lithography due to their high resistance and high resolution. But the low sensitivity makes them not suitable for high volume manufacturing (HVM). Organic-inorganic hybrid photoresists, containing both organic and inorganic components, are regarded as one of the most promising EUV resists. They combine both merits of organic and inorganic materials and have significant advantages in machinability, etching resistance, EUV absorption, and chemical/thermal stability. Organic-inorganic hybrid photoresists are considered as ideal materials for realizing industrial-grade patterns below 10 nm. This review mainly focuses on the development of organic-inorganic hybrid photoresists over the past decade.
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spelling doaj.art-da8c4325456f45faba6b5b2906b0e6c92022-12-21T22:20:28ZengJommPublishJournal of Microelectronic Manufacturing2578-37692578-37692021-03-014110.33079/jomm.21040101Recent Advances in Organic-inorganic Hybrid PhotoresistsZhihao Wang0Xindi Yao1Huiwen An2Yake Wang3Jinping Chen4Shuangqing Wang5Xudong Guo6Tianjun Yu7Yi Zeng8Guoqiang Yang9Yi Li10Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190Beijing National Laboratory for Molecular Sciences, (, BNLMS, ), Key laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, China, Beijing 100190Beijing National Laboratory for Molecular Sciences, (, BNLMS, ), Key laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Beijing National Laboratory for Molecular Sciences, (, BNLMS, ), Key laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China, Beijing 100190 University of Chinese Academy of Sciences, China, Beijing 100039Photoresists are radiation-sensitive materials used for forming patterns to build up IC devices. To date, most photoresists have been based on organic polymers, which have been dominating the semiconductor industries over the past few decades. It is obvious that extreme ultraviolet (EUV) lithography has become the next-generation lithography technology. The development of comprehensive performance EUV resist is one of the most critical issues. However, organic polymeric photoresists are difficult to meet the harsh requirements of EUV lithography. Pure inorganic photoresists such as metal salts, hydrogen silsesquioxane (HSQ) are expected for EUV lithography due to their high resistance and high resolution. But the low sensitivity makes them not suitable for high volume manufacturing (HVM). Organic-inorganic hybrid photoresists, containing both organic and inorganic components, are regarded as one of the most promising EUV resists. They combine both merits of organic and inorganic materials and have significant advantages in machinability, etching resistance, EUV absorption, and chemical/thermal stability. Organic-inorganic hybrid photoresists are considered as ideal materials for realizing industrial-grade patterns below 10 nm. This review mainly focuses on the development of organic-inorganic hybrid photoresists over the past decade.http://www.jommpublish.org/p/69/organic-inorganic hybrid photoresisteuv lithographynanoclusternanoparticleorganometallic complex
spellingShingle Zhihao Wang
Xindi Yao
Huiwen An
Yake Wang
Jinping Chen
Shuangqing Wang
Xudong Guo
Tianjun Yu
Yi Zeng
Guoqiang Yang
Yi Li
Recent Advances in Organic-inorganic Hybrid Photoresists
Journal of Microelectronic Manufacturing
organic-inorganic hybrid photoresist
euv lithography
nanocluster
nanoparticle
organometallic complex
title Recent Advances in Organic-inorganic Hybrid Photoresists
title_full Recent Advances in Organic-inorganic Hybrid Photoresists
title_fullStr Recent Advances in Organic-inorganic Hybrid Photoresists
title_full_unstemmed Recent Advances in Organic-inorganic Hybrid Photoresists
title_short Recent Advances in Organic-inorganic Hybrid Photoresists
title_sort recent advances in organic inorganic hybrid photoresists
topic organic-inorganic hybrid photoresist
euv lithography
nanocluster
nanoparticle
organometallic complex
url http://www.jommpublish.org/p/69/
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