New Pathways to Precursors of Pentalene

Syn-cis-(2) and anti-cis-(3) pentalene dimers are easily available by CuCl2-induced oxidative coupling of dilithium-pentalenediide (5). On the other hand, NBS-bromination as well of 1,5-dihydro-pentalene (4) as of 1,2-dihydropentalene (6) gives unstable 1-bromo-1,2-dihydropentalene (7), wh...

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Bibliographic Details
Main Authors: Shaochun You, Markus Neuenschwander
Format: Article
Language:deu
Published: Swiss Chemical Society 1996-01-01
Series:CHIMIA
Online Access:https://chimia.ch/chimia/article/view/2599