New Pathways to Precursors of Pentalene
Syn-cis-(2) and anti-cis-(3) pentalene dimers are easily available by CuCl2-induced oxidative coupling of dilithium-pentalenediide (5). On the other hand, NBS-bromination as well of 1,5-dihydro-pentalene (4) as of 1,2-dihydropentalene (6) gives unstable 1-bromo-1,2-dihydropentalene (7), wh...
| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1996-01-01
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| Series: | CHIMIA |
| Online Access: | https://chimia.ch/chimia/article/view/2599 |
| _version_ | 1818294424235409408 |
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| author | Shaochun You Markus Neuenschwander |
| author_facet | Shaochun You Markus Neuenschwander |
| author_sort | Shaochun You |
| collection | DOAJ |
| description |
Syn-cis-(2) and anti-cis-(3) pentalene dimers are easily available by CuCl2-induced oxidative coupling of dilithium-pentalenediide (5). On the other hand, NBS-bromination as well of 1,5-dihydro-pentalene (4) as of 1,2-dihydropentalene
(6) gives unstable 1-bromo-1,2-dihydropentalene (7), while subsequent in situ elimination with Et3N exclusively leads to syn-cis-pentalene dimer 2 in moderate yields.
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| first_indexed | 2024-12-13T03:31:32Z |
| format | Article |
| id | doaj.art-dc9ce66104524237b38e4f3a8b8abe90 |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-12-13T03:31:32Z |
| publishDate | 1996-01-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-dc9ce66104524237b38e4f3a8b8abe902022-12-22T00:01:09ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241996-01-01501-2New Pathways to Precursors of PentaleneShaochun YouMarkus Neuenschwander Syn-cis-(2) and anti-cis-(3) pentalene dimers are easily available by CuCl2-induced oxidative coupling of dilithium-pentalenediide (5). On the other hand, NBS-bromination as well of 1,5-dihydro-pentalene (4) as of 1,2-dihydropentalene (6) gives unstable 1-bromo-1,2-dihydropentalene (7), while subsequent in situ elimination with Et3N exclusively leads to syn-cis-pentalene dimer 2 in moderate yields. https://chimia.ch/chimia/article/view/2599 |
| spellingShingle | Shaochun You Markus Neuenschwander New Pathways to Precursors of Pentalene CHIMIA |
| title | New Pathways to Precursors of Pentalene |
| title_full | New Pathways to Precursors of Pentalene |
| title_fullStr | New Pathways to Precursors of Pentalene |
| title_full_unstemmed | New Pathways to Precursors of Pentalene |
| title_short | New Pathways to Precursors of Pentalene |
| title_sort | new pathways to precursors of pentalene |
| url | https://chimia.ch/chimia/article/view/2599 |
| work_keys_str_mv | AT shaochunyou newpathwaystoprecursorsofpentalene AT markusneuenschwander newpathwaystoprecursorsofpentalene |