Azo-dimethylaminopyridine-functionalized Ni(II)-porphyrin as a photoswitchable nucleophilic catalyst

Azo-dimethylaminopyridine-functionalized Ni(II)-porphyrin as a photoswitchable nucleophilic catalyst

We present the synthesis and the photochemical and catalytic switching properties of an azopyridine as a photoswitchable ligand, covalently attached to a Ni(II)-porphyrin. Upon irradiation with 530 nm (green light), the azopyridine switches to the cis configuration and coordinates with the Ni2+ ion....

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Bibliographic Details
Main Authors: Jannis Ludwig, Julian Helberg, Hendrik Zipse, Rainer Herges
Format: Article
Language:English
Published: Beilstein-Institut 2020-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
catalysis
ni(ii)-porphyrins
nucleophilic catalyst
photoswitch
record player molecules
spin switch
Online Access:https://doi.org/10.3762/bjoc.16.179

Internet

https://doi.org/10.3762/bjoc.16.179

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