Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality

Abstract A family of transition metal complexes of meso‐aryl‐2‐aza‐21‐carbaporphyrin (N‐confused porphyrin, NCP) derivatives acting as ortho‐metallating ligands for ruthenium(II), rhodium(III), and iridium(III) is synthesized and characterized by XRD, spectroscopic, and electrochemical methods. The...

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Bibliographic Details
Main Authors: Sebastian Koniarz, Kinga Szydełko, Michał J. Białek, Karolina Hurej, Piotr J. Chmielewski
Format: Article
Language:English
Published: Wiley 2024-01-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202306696