Preparation and Catalytic Activity of Boron-Substituted Zirconocenes

Borylated zirconocenes of the type (L2B–C5H4)2ZrCl2 and (L2B–C5H4)(C5H5)ZrCl2 are readily available in two steps. In the polymerization of ethylene and propylene in the presence of AlEt3 or methylalumoxan (MAO), these zirconocenes are more active than the unsubstituted reagent Cp2ZrCl2....

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Bibliographic Details
Main Authors: Manfred T. Reetz, Ranno Brümmer, Magnus Kessler, Jörg Kuhnigk
Format: Article
Language:deu
Published: Swiss Chemical Society 1995-12-01
Series:CHIMIA
Online Access:https://chimia.ch/chimia/article/view/2588