Hematin and CuII control generations of hydroperoxyl and superoxide radicals to activate galactose oxidase for 5-hydroxymethylfurfural conversion

Summary: We present a significant finding that Cu(II) ions can activate hematin (Hem) to generate more HOO⋅ and O2⋅- radicals from the decomposition of H2O2. Galactose oxidase (GO) and hematin have been simultaneously immobilized by coordinating to Cu(II) ions (GO&Hem@Cu(II)). The radicals HOO⋅...

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Bibliographic Details
Main Authors: Yao Chen, Jinxin Zou, Peijun Ji, Wei Feng
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:iScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004223025294