Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO2–MEA absorptions with CaCO3, MgCO3 and BaCO3

Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO2–MEA absorptions with CaCO3, MgCO3 and BaCO3

The mechanism was proposed of heterogeneous catalytic CO2 absorptions with primary/secondary amines involving ‘catalytic carbamate formation’. Compared with the non-catalytic ‘Zwitterion mechanism’, this Eley–Rideal model was proposed for CO2 + RR′NH with MCO3 (M = Ca, Mg, and Ba) with four elementa...

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Bibliographic Details
Main Authors: Huancong Shi, Min Huang, Yuandong Huang, Lifeng Cui, Linna Zheng, Mingqi Cui, Linhua Jiang, Hussameldin Ibrahim, Paitoon Tontiwachwuthikul
Format: Article
Language:English
Published: The Royal Society 2019-05-01
Series:Royal Society Open Science
Subjects:
co2 absorption and desorption
heterogeneous catalysis
eley–rideal model
zwitterion mechanism
solid surface reactions
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190311

Internet

https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190311

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