Stable Carbenes as Structural Components of Partially Saturated Sulfur-Containing Heterocycles

Stable Carbenes as Structural Components of Partially Saturated Sulfur-Containing Heterocycles

Recently, an unusual elongation of the C-S bond was observed experimentally for some sulfur-containing heterocycles. Using a superior ab initio (SCS-MP2/cc-pVTZ) level of theory, we showed that the phenomenon can be explained by a contribution of a donor–acceptor adduct of a carbene with an unsatura...

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Bibliographic Details
Main Authors: Alexander B. Rozhenko, Yuliia S. Horbenko, Andrii A. Kyrylchuk, Evgenij V. Zarudnitskii, Sergiy S. Mykhaylychenko, Yuriy G. Shermolovich, Andriy V. Grafov
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Molecules
Subjects:
stable carbenes
ab initio calculations
thiadiazolines
bond elongation
Online Access:https://www.mdpi.com/1420-3049/27/5/1458

Internet

https://www.mdpi.com/1420-3049/27/5/1458

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