Evidence of ammonia synthesis by bulk diffusion in cobalt molybdenum particles in a CLAS process

For the first time ammonia-synthesis-on-nitridation has been reported in CoMo during a chemical looping ammonia synthesis experiment. The observation lends evidence to the existence of a dynamic surface, a shrinking core and counter diffusion. The Mars-van Krevlen mechanism involving surface and bul...

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Bibliographic Details
Main Authors: Sean W. Brown, Changle Jiang, Qiang Wang, Ashley Caiola, Jianli Hu
Format: Article
Language:English
Published: Elsevier 2022-07-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736722000437