Hydrothermal synthesis, structure, and catalytic properties of a (4,6)-connected framework constructed from Keggin-type polyoxometalate units and tetranuclear copper complexes
Under hydrothermal conditions, a Keggin-type polyoxometalate-based metal–organic complex, H4{[Cu4(EDDP)2(H2O)5]1.5(SiW12O40)}∙7.5H2O (CuW-EDDP, H4EDDP = ethylene-diamine-N,N'-dipropionic acid), was synthesized by reacting Na10[A-α-SiW9O34]·18H2O and CuCl2·2H2O in the presence of H4EDDP ligands...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Tsinghua University Press
2024-03-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2023.9140039 |