Thermo-Reversible Persistent Phosphorescence Modulation Reveals the Large Contribution Made by Rigidity to the Suppression of Endothermic Intermolecular Triplet Quenching

The suppression of thermally driven triplet deactivation is crucial for efficient persistent room-temperature phosphorescence (pRTP). However, the mechanism by which triplet deactivation occurs in metal-free molecular solids at room temperature (RT) remains unclear. Herein, we report a large pRTP in...

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Bibliographic Details
Main Authors: Tomoya Kusama, Shuzo Hirata
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-11-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.788577/full