Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE

A high growth rate process above 1 µm/h was achieved for Si-doped (100) β-Ga2O3 homoepitaxial films grown via metalorganic vapor phase epitaxy (MOVPE) while maintaining high crystalline perfection up to a film thickness of 3 µm. The main growth parameters were investigated to increase the growth rat...

Full description

Bibliographic Details
Main Authors: Ta-Shun Chou, Palvan Seyidov, Saud Bin Anooz, Raimund Grüneberg, Thi Thuy Vi Tran, Klaus Irmscher, Martin Albrecht, Zbigniew Galazka, Jutta Schwarzkopf, Andreas Popp
Format: Article
Language:English
Published: AIP Publishing LLC 2021-11-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0069243
_version_ 1818682512201744384
author Ta-Shun Chou
Palvan Seyidov
Saud Bin Anooz
Raimund Grüneberg
Thi Thuy Vi Tran
Klaus Irmscher
Martin Albrecht
Zbigniew Galazka
Jutta Schwarzkopf
Andreas Popp
author_facet Ta-Shun Chou
Palvan Seyidov
Saud Bin Anooz
Raimund Grüneberg
Thi Thuy Vi Tran
Klaus Irmscher
Martin Albrecht
Zbigniew Galazka
Jutta Schwarzkopf
Andreas Popp
author_sort Ta-Shun Chou
collection DOAJ
description A high growth rate process above 1 µm/h was achieved for Si-doped (100) β-Ga2O3 homoepitaxial films grown via metalorganic vapor phase epitaxy (MOVPE) while maintaining high crystalline perfection up to a film thickness of 3 µm. The main growth parameters were investigated to increase the growth rate and maintain the step-flow growth mode, wherein the enhanced diffusion channel due to the formation of a Ga adlayer was proposed to be the possible growth mechanism. Si doping allowed precise control of the n-type conductivity of the films with electron concentrations ranging from 1.5 × 1017 to 1.5 × 1019 cm−3 and corresponding mobilities from 144 to 21 cm2 V−1 s−1, as revealed by Hall effect measurements at room temperature. Secondary ion mass spectrometry confirmed homogeneous Si doping through the film and a one-to-one correlation between the Si concentration and the electron concentration. Low defect density in the films was determined by x-ray diffraction measurements. The demonstration of a high growth rate process of β-Ga2O3 films with μm level thickness and smooth surface morphology via MOVPE is critical for high power electronics with vertical device architecture.
first_indexed 2024-12-17T10:20:01Z
format Article
id doaj.art-e1255397886d4803b88f3d7b688b2f68
institution Directory Open Access Journal
issn 2158-3226
language English
last_indexed 2024-12-17T10:20:01Z
publishDate 2021-11-01
publisher AIP Publishing LLC
record_format Article
series AIP Advances
spelling doaj.art-e1255397886d4803b88f3d7b688b2f682022-12-21T21:52:49ZengAIP Publishing LLCAIP Advances2158-32262021-11-011111115323115323-610.1063/5.0069243Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPETa-Shun Chou0Palvan Seyidov1Saud Bin Anooz2Raimund Grüneberg3Thi Thuy Vi Tran4Klaus Irmscher5Martin Albrecht6Zbigniew Galazka7Jutta Schwarzkopf8Andreas Popp9Leibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyLeibniz-Institut für Kristallzüchtung (IKZ), Max-Born-Str. 2, 12489 Berlin, GermanyA high growth rate process above 1 µm/h was achieved for Si-doped (100) β-Ga2O3 homoepitaxial films grown via metalorganic vapor phase epitaxy (MOVPE) while maintaining high crystalline perfection up to a film thickness of 3 µm. The main growth parameters were investigated to increase the growth rate and maintain the step-flow growth mode, wherein the enhanced diffusion channel due to the formation of a Ga adlayer was proposed to be the possible growth mechanism. Si doping allowed precise control of the n-type conductivity of the films with electron concentrations ranging from 1.5 × 1017 to 1.5 × 1019 cm−3 and corresponding mobilities from 144 to 21 cm2 V−1 s−1, as revealed by Hall effect measurements at room temperature. Secondary ion mass spectrometry confirmed homogeneous Si doping through the film and a one-to-one correlation between the Si concentration and the electron concentration. Low defect density in the films was determined by x-ray diffraction measurements. The demonstration of a high growth rate process of β-Ga2O3 films with μm level thickness and smooth surface morphology via MOVPE is critical for high power electronics with vertical device architecture.http://dx.doi.org/10.1063/5.0069243
spellingShingle Ta-Shun Chou
Palvan Seyidov
Saud Bin Anooz
Raimund Grüneberg
Thi Thuy Vi Tran
Klaus Irmscher
Martin Albrecht
Zbigniew Galazka
Jutta Schwarzkopf
Andreas Popp
Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
AIP Advances
title Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
title_full Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
title_fullStr Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
title_full_unstemmed Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
title_short Fast homoepitaxial growth of (100) β-Ga2O3 thin films via MOVPE
title_sort fast homoepitaxial growth of 100 β ga2o3 thin films via movpe
url http://dx.doi.org/10.1063/5.0069243
work_keys_str_mv AT tashunchou fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT palvanseyidov fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT saudbinanooz fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT raimundgruneberg fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT thithuyvitran fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT klausirmscher fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT martinalbrecht fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT zbigniewgalazka fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT juttaschwarzkopf fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe
AT andreaspopp fasthomoepitaxialgrowthof100bga2o3thinfilmsviamovpe