Zirconocene-Catalyzed Dimerization of α-Olefins: DFT Modeling of the Zr-Al Binuclear Reaction Mechanism
Zirconocene-mediated selective dimerization of α-olefins usually occurs when precatalyst (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>ZrCl<sub>2</sub> is activated by minimal excess of methylalumoxane (MAO). In th...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-10-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/24/19/3565 |