Synthesis and Reactivity of Mn–CF3 Complexes

The synthesis, characterization and reactivity of several bi- and tridentate, N-ligated manganese carbonyl trifluoromethyl complexes are presented. These complexes exhibit elongated Mn–CCF3 bonds (versus Mn(CF3)(CO)5), suggesting a lability that could be utilized for the transfer or insert...

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Bibliographic Details
Main Authors: Alex L. Daniels, Jason G. Da Gama, Racquel Edjoc, Bulat M. Gabidullin, R. Tom Baker
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Inorganics
Subjects:
Online Access:http://www.mdpi.com/2304-6740/7/1/3