Synthesis, Reactivity and Coordination Chemistry of Group 9 PBP Boryl Pincer Complexes: [(PBP)M(PMe<sub>3</sub>)<i><sub>n</sub></i>] (M = Co, Rh, Ir; <i>n</i> = 1, 2)
The unsymmetrical diborane(4) derivative [(d(CH<sub>2</sub>P(<i>i</i>Pr)<sub>2</sub>)abB)–Bpin] (<b>1</b>) proved to be a versatile PBP boryl pincer ligand precursor for Co(I) (<b>2a</b>, <b>4a</b>), Rh(I) (<b>2</b>–...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-08-01
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Series: | Molecules |
Subjects: | |
Online Access: | https://www.mdpi.com/1420-3049/28/17/6191 |