Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols

Molecular rearrangements are ubiquitous in modern synthetic chemistry, providing a powerful strategy to arrive at complex structures in an atom- and step-economic process. Here, the authors disclose a Mn(I)- catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols via C-C σ-bond activation t...

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Bibliographic Details
Main Authors: Can Yang, Xiaoyu Zhou, Lixing Shen, Zhuofeng Ke, Huanfeng Jiang, Wei Zeng
Format: Article
Language:English
Published: Nature Portfolio 2023-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-37299-x