Visible Light Promotes Cascade Trifluoromethylation/Cyclization, Leading to Trifluoromethylated Polycyclic Quinazolinones, Benzimidazoles and Indoles

Visible Light Promotes Cascade Trifluoromethylation/Cyclization, Leading to Trifluoromethylated Polycyclic Quinazolinones, Benzimidazoles and Indoles

Efficient visible-light-induced radical cascade trifluoromethylation/cyclization of inactivated alkenes with CF<sub>3</sub>Br, which is a nonhygroscopic, noncorrosive, cheap and industrially abundant chemical, was developed in this work, producing trifluoromethyl polycyclic quinazolinone...

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Bibliographic Details
Main Authors: Ransong Ma, Yuanyuan Ren, Zhoubin Deng, Ke-Hu Wang, Junjiao Wang, Danfeng Huang, Yulai Hu, Xiaobo Lv
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Molecules
Subjects:
bromotrifluoromethane
visible-light induction
trifluoromethylation
cyclization
polycyclic quinazolinone
polycyclic benzimidazole
Online Access:https://www.mdpi.com/1420-3049/27/23/8389

Internet

https://www.mdpi.com/1420-3049/27/23/8389

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