Oxidative Coupling of 6,6-Dimethylfulvenyl Anion

Oxidative treatment of anion 1 (obtained by deprotonation of 6,6-dimethylpentafulvene) with CuCl2 gives a very complex mixture of coupling products 3 (18%), 4 (16%), 5 (36%), 6 (5%), and 7 (6%) (Scheme 2). This result shows that the reactive intermediate obtained by oxidation of 1 (which i...

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Bibliographic Details
Main Authors: Shaochun You, Markus Neuenschwander
Format: Article
Language:deu
Published: Swiss Chemical Society 1992-09-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/2161