Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides

A series of bulky geometry-constrained iminopyridylpalladium chlorides were developed. The steric environment adjacent to the nitrogen atom in the pyridine rings and diimine parts enhanced the thermal stability of the palladium species. Bulkier groups at the imino group stabilized the palladium spec...

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Bibliographic Details
Main Authors: Yi Lai, Zhijian Zong, Yujie Tang, Weimin Mo, Nan Sun, Baoxiang Hu, Zhenlu Shen, Liqun Jin, Wen-hua Sun, Xinquan Hu
Format: Article
Language:English
Published: Beilstein-Institut 2017-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.13.24