Dienophilic reactivity of 2-phosphaindolizines: a conceptual DFT investigation

Dienophilic reactivity of 2-phosphaindolizines: a conceptual DFT investigation

The >C=P– or –N=P– functionality in 1,3-azaphospholo[1,5-a]pyridine, named as 2-phosphaindolizine and its 1- and 3-aza derivatives act as dienophiles and undergo Diels–Alder reactions with 1,3-dienes. However, the dienophilic reactivity is affected by the nature of the substituent groups on the t...

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Bibliographic Details
Main Authors: Nosheen Beig, Aarti Peswani, Raj Kumar Bansal
Format: Article
Language:English
Published: Beilstein-Institut 2022-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
dienophilic reactivity
electronic chemical potential
electrophilicity index
fukui function
global hardness
nucleophilicity index
2-phosphaindolizines
Online Access:https://doi.org/10.3762/bjoc.18.127

Internet

https://doi.org/10.3762/bjoc.18.127

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