Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ2N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ2O:O2]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology

Poly[[[μ-1,4-bis(pyridin-4-ylcarbonyl)piperazine-κ2N:N′][μ-2-(2-carboxylatoeth-1-en-1-yl)benzoato-κ2O:O2]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology

The title compound, {[Zn(C10H6O4)(C16H16N4O2]·2.5H2O}n, contains five-coordinate ZnII ions intermediate between square-pyramidal and trigonal–bipyramidal coordination environments. The ZnII ions are connected by 2-carboxycinnamate (cca) ligands and N,N′-bis-(pyridine-4-carboxamido)piperazine (4-pcap...

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Bibliographic Details
Main Authors: Erika J. Glatz, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2023-09-01
Series:IUCrData
Subjects:
crystal structure
tri-periodic coordination polymer
pcu topology
cca
4-pcap
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314623008118

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314623008118

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