Relation between the Co-O bond lengths and the spin state of Co in layered Cobaltates: a high-pressure study

Abstract The pressure-response of the Co-O bond lengths and the spin state of Co ions in a hybrid 3d-5d solid-state oxide Sr2Co0.5Ir0.5O4 with a layered K2NiF4-type structure was studied by using hard X-ray absorption and emission spectroscopies. The Co-K and the Ir-L 3 X-ray absorption spectra demo...

Full description

Bibliographic Details
Main Authors: Yi-Ying Chin, Hong-Ji Lin, Zhiwei Hu, Chang-Yang Kuo, Daria Mikhailova, Jenn-Min Lee, Shu-Chih Haw, Shin-An Chen, Walter Schnelle, Hirofumi Ishii, Nozomu Hiraoka, Yen-Fa Liao, Ku-Ding Tsuei, Arata Tanaka, Liu Hao Tjeng, Chien-Te Chen, Jin-Ming Chen
Format: Article
Language:English
Published: Nature Portfolio 2017-06-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-017-03950-z