Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones

Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones

Enantiopure (R,R) and (S,S)-dimethyl-bis(ethylenedithio)tetrathiafulvalene monosulfones have been synthesized by the aerial oxidation of the chiral dithiolates generated from the propionitrile-protected precursors. Both enantiomers crystallize in the orthorhombic chiral space group P212121. They sho...

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Bibliographic Details
Main Authors: Flavia Pop, Narcis Avarvari
Format: Article
Language:English
Published: Beilstein-Institut 2015-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chirality
crystal structures
molecular materials
sulfones
tetrathiafulvalenes
Online Access:https://doi.org/10.3762/bjoc.11.124

Internet

https://doi.org/10.3762/bjoc.11.124

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