Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency

Antimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency sti...

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Main Authors: Pascal Kaienburg, Benjamin Klingebiel, Thomas Kirchartz
Format: Article
Language:English
Published: Beilstein-Institut 2018-08-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.9.200
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author Pascal Kaienburg
Benjamin Klingebiel
Thomas Kirchartz
author_facet Pascal Kaienburg
Benjamin Klingebiel
Thomas Kirchartz
author_sort Pascal Kaienburg
collection DOAJ
description Antimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency still lags behind. We compare two processing routes based on different precursors reported in the literature. By studying the film morphology, sub-bandgap absorption and solar cell performance, improved annealing procedures are found and the crystallization temperature is shown to be critical. In order to determine the optimized processing conditions, the role of the polymeric hole transport material is discussed. The efficiency of our best solar cells exceeds previous reports for each processing route, and our champion device displays one of the highest efficiencies reported for planar antimony sulfide solar cells.
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spelling doaj.art-e651ff9e2ffa4fc9bc8bdf894bf3a5c22022-12-22T01:16:45ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862018-08-01912114212410.3762/bjnano.9.2002190-4286-9-200Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiencyPascal Kaienburg0Benjamin Klingebiel1Thomas Kirchartz2IEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyIEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyIEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyAntimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency still lags behind. We compare two processing routes based on different precursors reported in the literature. By studying the film morphology, sub-bandgap absorption and solar cell performance, improved annealing procedures are found and the crystallization temperature is shown to be critical. In order to determine the optimized processing conditions, the role of the polymeric hole transport material is discussed. The efficiency of our best solar cells exceeds previous reports for each processing route, and our champion device displays one of the highest efficiencies reported for planar antimony sulfide solar cells.https://doi.org/10.3762/bjnano.9.200antimony sulfidehole transport materialsolar cell
spellingShingle Pascal Kaienburg
Benjamin Klingebiel
Thomas Kirchartz
Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
Beilstein Journal of Nanotechnology
antimony sulfide
hole transport material
solar cell
title Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
title_full Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
title_fullStr Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
title_full_unstemmed Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
title_short Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
title_sort spin coated planar sb2s3 hybrid solar cells approaching 5 efficiency
topic antimony sulfide
hole transport material
solar cell
url https://doi.org/10.3762/bjnano.9.200
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AT benjaminklingebiel spincoatedplanarsb2s3hybridsolarcellsapproaching5efficiency
AT thomaskirchartz spincoatedplanarsb2s3hybridsolarcellsapproaching5efficiency