Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency
Antimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency sti...
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Format: | Article |
Language: | English |
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Beilstein-Institut
2018-08-01
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Series: | Beilstein Journal of Nanotechnology |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjnano.9.200 |
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author | Pascal Kaienburg Benjamin Klingebiel Thomas Kirchartz |
author_facet | Pascal Kaienburg Benjamin Klingebiel Thomas Kirchartz |
author_sort | Pascal Kaienburg |
collection | DOAJ |
description | Antimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency still lags behind. We compare two processing routes based on different precursors reported in the literature. By studying the film morphology, sub-bandgap absorption and solar cell performance, improved annealing procedures are found and the crystallization temperature is shown to be critical. In order to determine the optimized processing conditions, the role of the polymeric hole transport material is discussed. The efficiency of our best solar cells exceeds previous reports for each processing route, and our champion device displays one of the highest efficiencies reported for planar antimony sulfide solar cells. |
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format | Article |
id | doaj.art-e651ff9e2ffa4fc9bc8bdf894bf3a5c2 |
institution | Directory Open Access Journal |
issn | 2190-4286 |
language | English |
last_indexed | 2024-12-11T06:56:42Z |
publishDate | 2018-08-01 |
publisher | Beilstein-Institut |
record_format | Article |
series | Beilstein Journal of Nanotechnology |
spelling | doaj.art-e651ff9e2ffa4fc9bc8bdf894bf3a5c22022-12-22T01:16:45ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862018-08-01912114212410.3762/bjnano.9.2002190-4286-9-200Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiencyPascal Kaienburg0Benjamin Klingebiel1Thomas Kirchartz2IEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyIEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyIEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, GermanyAntimony sulfide solar cells have demonstrated an efficiency exceeding 7% when assembled in an extremely thin absorber configuration deposited via chemical bath deposition. More recently, less complex, planar geometries were obtained from simple spin-coating approaches, but the device efficiency still lags behind. We compare two processing routes based on different precursors reported in the literature. By studying the film morphology, sub-bandgap absorption and solar cell performance, improved annealing procedures are found and the crystallization temperature is shown to be critical. In order to determine the optimized processing conditions, the role of the polymeric hole transport material is discussed. The efficiency of our best solar cells exceeds previous reports for each processing route, and our champion device displays one of the highest efficiencies reported for planar antimony sulfide solar cells.https://doi.org/10.3762/bjnano.9.200antimony sulfidehole transport materialsolar cell |
spellingShingle | Pascal Kaienburg Benjamin Klingebiel Thomas Kirchartz Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency Beilstein Journal of Nanotechnology antimony sulfide hole transport material solar cell |
title | Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency |
title_full | Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency |
title_fullStr | Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency |
title_full_unstemmed | Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency |
title_short | Spin-coated planar Sb2S3 hybrid solar cells approaching 5% efficiency |
title_sort | spin coated planar sb2s3 hybrid solar cells approaching 5 efficiency |
topic | antimony sulfide hole transport material solar cell |
url | https://doi.org/10.3762/bjnano.9.200 |
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