The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene/1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives

The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene/1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives

In the present study, copolymerization of ethylene and 1-hexene was conducted with a series of ansa-fluorenylamidodimethyltitanium complexes, including [t-BuNSiMe2Flu]TiMe2 (complex 1), [cyclododecylNSiMe2Flu]TiMe2 (complex 2) and [t-BuNSiMe2(2,7-t-Bu2Flu)]TiMe2 (complex 3), activated by MMAO. The e...

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Bibliographic Details
Main Authors: Bunjerd Jongsomjit, Zhengguo Cai, Takeshi Shiono, Piyasan Praserthdam, Yuuichi Sogo, Patcharaporn Kaivalchatchawal
Format: Article
Language:English
Published: MDPI AG 2011-05-01
Series:Molecules
Subjects:
polymer synthesis
catalytic synthesis
polyolefins
metallocene catalyst
CGC catalyst
Online Access:http://www.mdpi.com/1420-3049/16/5/4122/

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http://www.mdpi.com/1420-3049/16/5/4122/

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