The disilanes Cp*SiCl2SiH3 and Cp*SiH2SiH2Cp*
Hydrogenation of Cp*SiCl2SiCl3 (A) (Cp*=C5Me5) with diisobutylaluminum hydride (DIBAL-H) gave partially hydrogenated disilane Cp*SiCl2SiH3 (1) with 45% yield, whereas the reaction with lithium aluminum hydride (LiAlH4) provided the well-known Cp*SiH2SiH3. The symmetric disilane Cp*SiH2SiH2Cp* (2) is...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2015-08-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2015-0015 |