Aminothiolation of alkenes with azoles and Bunte salts

We have developed an intermolecular aminothiolation of simple olefins using Bunte salt as a thiolating agent. This protocol produces thiyl free radicals under PIDA oxidation conditions, eliminating the need for transition-metal catalysts. The method has a wide range of substrate applicability and is...

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Bibliographic Details
Main Authors: Bingqing Ouyang, Xing Chai, Zhe Li, Chunling Zhang, Xingmei Liu
Format: Article
Language:English
Published: Frontiers Media S.A. 2024-01-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2023.1328441/full