Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction

An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.

書誌詳細
主要な著者: Gamenara Daniela, Días Eduardo, Tancred Néstor, Heinzen Horacio, Moyna Patrick, Forbes Eric J.
フォーマット: 論文
言語:English
出版事項: Sociedade Brasileira de Química 2001-01-01
シリーズ:Journal of the Brazilian Chemical Society
主題:
オンライン・アクセス:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008