Binding Between Cyclohexanohemicucurbit[n]urils and Polar Organic Guests

Binding Between Cyclohexanohemicucurbit[n]urils and Polar Organic Guests

Inherently chiral, barrel-shaped, macrocyclic hosts such as cyclohexanohemicucurbit[n]urils (cycHC[n]) bind zinc porphyrins and trifluoroacetic acid externally in halogenated solvents. In the current study, we tested a set of eighteen organic guests with various functional groups and polarity, namel...

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Bibliographic Details
Main Authors: Lukas Ustrnul, Tatsiana Burankova, Mario Öeren, Kristina Juhhimenko, Jenni Ilmarinen, Kristjan Siilak, Kamini A. Mishra, Riina Aav
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-06-01
Series:Frontiers in Chemistry
Subjects:
supramolecular chemistry
binding evaluation
hemicucurbit[n]uril
hydrogen bond
complex stoichiometry
NMR
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.701028/full

Internet

https://www.frontiersin.org/articles/10.3389/fchem.2021.701028/full

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