Hydrogen-Bonding in Two Pyridinium Salts of [Mo2O4Cl4(μ2-dmsH)]3−Complex (dmsH− = a Half-Neutralized Form of 2,2-Dimethylsuccinic Acid)
Reactions of a mononuclear molybdenum(V) starting material, (PyH)5[MoOCl4(H2O)]3Cl2, with 2,2-dimethylsuccinic acid in the presence of base afforded two products, (PyH)3[Mo2O4Cl4(μ2-dmsH)]·1/2CH3CN (1) and (PyH)4[Mo2O4Cl4(μ2-dmsH)]Cl (2). As revealed by the X-ray structure analysis, the half-neutral...
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| Format: | Article |
| Language: | English |
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MDPI AG
2013-04-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/3/2/275 |