Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbita...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2019-06-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-10589-z |