Photocycloaddition of aromatic and aliphatic aldehydes to isoxazoles: Cycloaddition reactivity and stability studies

The first photocycloadditions of aromatic and aliphatic aldehydes to methylated isoxazoles are reported. The reactions lead solely to the exo-adducts with high regio- and diastereoselectivities. Ring methylation of the isoxazole substrates is crucial for high conversions and product stability. The 6...

Full description

Bibliographic Details
Main Authors: Axel G. Griesbeck, Marco Franke, Jörg Neudörfl, Hidehiro Kotaka
Format: Article
Language:English
Published: Beilstein-Institut 2011-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.7.18