Elucidation of the origin of chiral amplification in discrete molecular polyhedra

The sergeants-and-soldiers effect, in which a few chiral units induce chirality in a large number of achiral molecules, is difficult to quantify at the molecular level. Here, the authors devise an elegant strategy—combining theory and a system of pure organic polyhedra with chiral and achiral vertic...

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Bibliographic Details
Main Authors: Yu Wang, Hongxun Fang, Ionut Tranca, Hang Qu, Xinchang Wang, Albert J. Markvoort, Zhongqun Tian, Xiaoyu Cao
Format: Article
Language:English
Published: Nature Portfolio 2018-02-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-02605-x