Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

Methods for the asymmetric introduction of organofluorine groups are often limited by the lack of variability in the starting materials. Here the authors report an asymmetric radical process for the introduction of fluoroalkyl groups using readily available fluoroalkylated sulfonyl chlorides.

ग्रंथसूची विवरण
मुख्य लेखकों: Jin-Shun Lin, Fu-Li Wang, Xiao-Yang Dong, Wei-Wei He, Yue Yuan, Su Chen, Xin-Yuan Liu
स्वरूप: लेख
भाषा:English
प्रकाशित: Nature Portfolio 2017-03-01
श्रृंखला:Nature Communications
ऑनलाइन पहुंच:https://doi.org/10.1038/ncomms14841