Crystal structure and Hirshfeld surface analysis of cyclo-tetrabromido-1κ2Br,3κ2Br-tetrakis(μ2-2-{[(pyridin-2-yl)methyl]amino}ethane-1-thiolato-κ3N,S:S)tetramercury(II)

Crystal structure and Hirshfeld surface analysis of cyclo-tetrabromido-1κ2Br,3κ2Br-tetrakis(μ2-2-{[(pyridin-2-yl)methyl]amino}ethane-1-thiolato-κ3N,S:S)tetramercury(II)

The macrometallacyclic title compound, [Hg4Br4(C8H11N2S)4] or [((HgL2)(HgBr2))2] (1) where HL = 2-{[(pyridin-2-yl)methyl]amino}ethane-1-thiol, was prepared and structurally characterized. The Hg2+ complex crystallizes in the P21/c space group. The centrosymmetric Hg4S4 metallacycle is constructed fr...

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Bibliographic Details
Main Authors: Isla D. Thomas, Kathryn R. Kocher, Julie A. Viehweg, Robert D. Pike, Deborah C. Bebout
Format: Article
Language:English
Published: International Union of Crystallography 2023-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
hirshfeld surface analysis
metallacycle
chelating n,s-ligands
hg2+ complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902300823X

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http://scripts.iucr.org/cgi-bin/paper?S205698902300823X

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