Search for Osme Bonds with π Systems as Electron Donors

The Osme bond is defined as pairing a Group 8 metal atom as an electron acceptor in a noncovalent interaction with a nucleophile. DFT calculations with the ωB97XD functional consider MO<sub>4</sub> (M = Ru, Os) as the Lewis acid, paired with a series of π electron donors C<sub>2<...

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Bibliographic Details
Main Authors: Xin Wang, Qingzhong Li, Steve Scheiner
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/1/79