Search for Osme Bonds with π Systems as Electron Donors
The Osme bond is defined as pairing a Group 8 metal atom as an electron acceptor in a noncovalent interaction with a nucleophile. DFT calculations with the ωB97XD functional consider MO<sub>4</sub> (M = Ru, Os) as the Lewis acid, paired with a series of π electron donors C<sub>2<...
Main Authors: | Xin Wang, Qingzhong Li, Steve Scheiner |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-12-01
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Series: | Molecules |
Subjects: | |
Online Access: | https://www.mdpi.com/1420-3049/29/1/79 |
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