Stabilizing Halogen-Bonded Complex between Metallic Anion and Iodide

Stabilizing Halogen-Bonded Complex between Metallic Anion and Iodide

Halogen bonds (XBs) between metal anions and halides have seldom been reported because metal anions are reactive for XB donors. The pyramidal-shaped Mn(CO)<sub>5</sub><sup>−</sup> anion is a candidate metallic XB acceptor with a ligand-protected metal core that maintains the...

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Bibliographic Details
Main Authors: Fei Ying, Xu Yuan, Xinxing Zhang, Jing Xie
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
halogen bond
metallic anion
nucleophilic substitution reaction
quantum chemistry calculation
reductive elimination
Online Access:https://www.mdpi.com/1420-3049/27/22/8069

Internet

https://www.mdpi.com/1420-3049/27/22/8069

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