Introducing Weakly Ligated Tris(trifluoromethyl)copper(III)

Introducing Weakly Ligated Tris(trifluoromethyl)copper(III)

Abstract Tris(trifluoromethyl)copper(III), Cu(CF3)3, was prepared for the first time and fully characterized in the form of weakly coordinated highly reactive solvent neutral adducts (DMF)2Cu(CF3)3 and (MeCN)Cu(CF3)3. Free Cu(CF3)3 is an elusive molecule of distorted T‐shaped geometry with Lewis aci...

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Bibliographic Details
Main Authors: Dr. Vladimir Motornov, Martin Procházka, Nora Alpuente, Dr. Pedro Salvador, Prof. Petr Slavíček, Dr. Blanka Klepetářová, Prof. Xavi Ribas, Dr. Petr Beier
Format: Article
Language:English
Published: Wiley-VCH 2024-03-01
Series:ChemistryEurope
Subjects:
Copper
High-valent copper
Lewis acids
Trifluoromethylation
Oxidation State
Online Access:https://doi.org/10.1002/ceur.202400004

Internet

https://doi.org/10.1002/ceur.202400004

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